• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The present invention relates to an UV blocking film comprising microfibriHated cellulose wherein at least part of the microfibrillated cellulose is microfibrillated cellulose produced from non-chemical modified lignocellulosic material. The invention also relates to a method for producing the film, use of said film as well as a composition having UV blocking properties.
    公开号:SE1650690A1
    申请号:SE1650690
    申请日:2016-05-20
    公开日:2017-11-21
    发明作者:Heiskanen Isto；Lyytikäinen Katja；Saukkonen Esa；Backfolk Kaj
    申请人:Stora Enso Oyj；
    IPC主号:
    专利说明:

    AN UV BLOCKING FILM, A METHOD FOR PRODUCING SAID FILM, ACOMPOSITION AND USE OF THE COMPOSITION Technical fieldThe present invention relates a film having good UV resistance and agood oxygen transmission rate (OTR) value. The invention further relates to a method for producing said film and a composition with UV blocking properties.
    BackgroundThe amount of UV radiation from the sun that reaches the surface of the earth varies around the globe and through time. Several factors accountfor this variation, e.g. cloud cover or ozone layer. UV (ultraviolet) radiation islight with wavelengths shorter than those visible to the human eye. UVradiation is divided into three categories by wavelengths: UVA (320 - 400nm), UVB (290 - 320 nm) and UVC (100-290 nm). The wavelengths of UVAare longer than UVB and can penetrate deeper into the layers of our skin.UVA radiation contributes to skin aging, photochemical smog, fading anddamage to woods, plastics, paints and fabrics. Only 1% of the solar radiationis within the UVB band, and most of this is blocked by the ozone layer.Nevertheless, UVB wavelengths are those that can cause the most damageto human skin. UVC radiation is totally blocked by the ozone and other gasesin the atmosphere, and does not reach the surface of the earth.
    UV radiation has both positive and negative effects. However, due tothe negative impact that UV radiation sometimes has it is important to findsolutions how to prevent the UV radition to cause damages. The mostcommon solution is to use UV blockers that will block the UV radiation andthus reduces the UV degradation of the exposed material. UV blockers areoften used as additives in window films, in paints, coatings, plastic or plasticfilms, sunscreens and in paper or paperboard products. Components used asUVA/UVB blockers are e.g. avobenzone, oxybenzone, titanium dioxide andzinc oxide and they will prevent e.g. the skin or material from being negativelyaffected by the UV radiation. However, the UV blockers used today are bothcostly and might also have a negative effect on the environment or might notbe approved for use in certain applications.
    Thus, there is a need for a more environmental friendly and costefficient UV blocker.
    Summarylt is an object of the present invention, to provide a film comprising microfibrillated cellulose produced from non-chemical modified lignocellulosicmaterial, which film has good UV blocking properties at the same time as theoxygen transmission rate (OTR) values are good especially at high moisturecontents. Another object of the present invention is to produce a film with UVblocking properties in a good way. Yet another object of the present inventionis a composition having UV blocking properties which composition comprisesnon-chemical modified lignocellulosic material as well as use of saidcomposition.
    The invention is defined by the appended independent claims.Preferred embodiments are set forth in the appended dependent claims andin the following description and drawings.
    The present invention relates to an UV blocking film comprisingmicrofibrillated cellulose (MFC) wherein at least part of the microfibrillatedcellulose is microfibrillated cellulose produced from non-chemical modifiedlignocellulosic material. lt has surprisingly been found that an UV film comprising microfibrillated cellulose produced from non-chemical modified lignocellulosic material can beused in order to give the MFC film good UV blocking properties at the sametime as the MFC film will be transparent or at least semi-transparent ortranslucent, i.e. the presence of MFC from the non-chemical modifiedlignocellulosic material will still make it possible to produce transparent filmswith good OTR values at high moisture contents. The use of MFC from non-chemical modified lignocellulosic material as an UV blocker has manyadvantages. First of all MFC from non-chemical modified lignocellulosicmaterial is a renewable material which makes it much more environmentalfriendly compared to UV blockers most commonly used today. Furthermore,MFC from non-chemical modified lignocellulosic material is quite cost efficient and it is also a safe material to handle, i.e. there are no health risks withhandling the MFC from non-chemical modified lignocellulosic material duringthe production and use. There are already today non-chemical modifiedlignocellulosic materials that are approved in e.g. food applications or fordirect skin contact applications, i.e. it is considered to a safe material. Also,the MFC from non-chemical modified lignocellulosic material tends to absorb less water making the film more moisture resistance.
    The non-chemical modified MFC is preferably produced frommechanical pulp which can be chemithermomechanical pulp (CTMP),thermomechanical pulp (TMP), pressure groundwood (PGW) pulp and/orstone groundwood pulp (SGP).
    The non-chemical modified lignocellulosic material may be fiber from acoconut shell.
    The film preferably comprises between 2.5-50% by weight of the fiberbased material of microfibrillated cellulose produced from non-chemicalmodified lignocellulosic material, preferably between 5-40% by weight or evenmore preferably between 5-20% by weight. lt has surprisingly been found thatit is sufficient that the MFC film comprises small amounts of MFC from non-chemical modified lignocellulosic material, preferably mechanical MFC, inorder for the film to have good UV blocking properties. When producing a filmcomprising MFC there is a desire to produce a film having good UV blockingproperties, which can be seen as a low transmittance (%) in the UV area. Thefilm should at the same time be transparent or at least semi-transparent,which can be seen as a high transmittance (%) in the visible light area, i.e. athigher wave lengths compared to the UV wave lengths. This is normally noteasy to achieve and definitely not in an easy, cost efficient and environmentalfriendly way.
    The film may also comprise microfibrillated cellulose produced fromchemical modified lignocellulosic material, preferably MFC from chemical pulp.
    The film preferably comprises 50-97.5% by weight of fiber basedmaterial of microfibrillated cellulose produced from chemical modifiedlignocellulosic material, preferably MFC from chemical pulp, preferablybetween 60-95% by weight or even more preferred between 80-95% byweight. Chemical MFC has the advantage that it gives the MFC film goodbarrier properties, especially good oxygen barrier properties. Also, thepresence of chemical MFC will improve the film forming properties of the film.Furthermore, the use of chemical MFC will also make the MFC film moretransparent compared to if mechanical MFC were used. Yet anotheradvantage with the present invention is that the production of chemical MFCis quite cost effective.
    The film may also comprise nano-fillers, preferably nano-precipitatedcalcium carbonate (PCC), nano-fillers from bentonite, nano-fillers fromtitanium dioxide, nano-fillers from zinc oxide, nanotalc, nano clays and/orother nano sized fillers.
    The film preferably has a basis weight of less than 50 g/m2, or less than35 g/m2, or less than 25 g/m2.
    The film preferably has a transmittance of at least 70% for radiation withwavelengths above 400nm meaning that the film is translucent or transparentfor the human eye (in the visible light area). The film preferably has atransmittance below 70% for radiation with wavelengths below 400nmmeaning that the film blocks radiation within the UV area.
    The present invention also relates to a method for manufacturing a filmhaving UV blocking properties wherein the method comprises the steps of;providing a first suspension comprising microfibrillated cellulose produced from non-chemical modified lignocellulosic material, conducting the firstsuspension to a wire and dewatering the first suspension to form a film.
    The method may also comprise the steps of; providing a secondsuspension comprising microfibrillated cellulose produced from chemicalmodified lignocellulosic material, mixing the first and second suspensionwhereby a mixture is obtained and thereafter conducting the mixture to a wireand thereafter dewatering the mixture to form the film. The first suspension isthus conducted to the wire as a mixture together with the second suspension.
    The microfibrillated cellulose preferably has a Schopper Riegler value(SR°) of more than 87 SR°, preferably more than 90 SR°, more than 93 SR°,or more than 95 SR°.
    The mixture obtained in the method according to the present inventionpreferably comprises the first suspension in an amount of 2.5-50% by weightof the total weight of the mixture and the second suspension in an amount of50-97.5% by weight of the total weight of the mixture.
    Nano-filler, preferably nano-precipitated calcium carbonate (PCC) isadded to the first suspension and/or second suspension. Other nano-fillerssuch as nano-fillers from bentonite, nano-fillers from titanium dioxide, nano-fillers from zinc oxide, nanotalc, nano clays and/or other nano sized fillersmay also be added.
    The present invention also relates to a composition having UV blockingproperties wherein said composition comprises microfibrillated celluloseproduced from non-chemical modified lignocellulosic material. lt hassurprisingly been found that MFC from non-chemical modified lignocellulosicmaterial, preferably mechanical MFC, can be used in compositions and givingthe composition UV blocking properties.
    The composition preferably comprises 2.5-50% by weight of fiber basedmaterial of microfibrillated cellulose produced from non-chemical modified lignocellulosic material, preferably between 5-40% by weight and even morepreferred between 5-20% by weight. lt has been found that it is sufficient toadd small amounts of MFC from non-chemical modified lignocellulosicmaterial, preferably mechanical MFC, to a composition and the compositionwill still have very good UV blocking properties.
    The composition may be a paint, a sunscreen, a coating color, a sizingcomposition, a yarn, a composite comprising a polymer used for e.g. screwcaps or a wood impregnation solution.
    The present invention also relates to the use of the film describes aboveas a window film, on the surface of a paper or paperboard product or as amulch or laminated onto a mulch.
    Detailed descriptionWith UV blocking film is meant that the film is blocking radiation within the UV range, i.e. radiation with wavelengths between 100-400nm includingboth UVA and UVB radiation. The UV blocking film according to the inventionblocks at least 65% of the UV radiation at a thickness of about 20um.
    With lignocellulosic material is meant a material comprising lignin,cellulose and hemicellulose. The lignocellulosic material is preferably acellulose material, i.e. a hardwood and/or softvvood wood material. Thelignocellulosic material may also be a bagasse, bamboo, corn cobs, cornstovers, fibers from coconut shells or other lignocellulosic material.
    MFC produced from non-chemical modified lignocellulosic materialmeans that the production of MFC is done from a lignocellulosic material thathas not been chemically modified prior to the MFC production, meaning thatthe lignocellulosic material has not been modified with any chemical thatdegrades the lignocellulosic material excluding any normal treatment used inpulp production, i.e. digesting, use of chelating agents and/or bleaching of thefibers. The production of MFC from the non-chemical modified lignocellulosicmaterial can then be produced in any conventional matter, i.e. by mechanical, enzymatic and/or chemical treatments wherein the chemical treatment is onlydone to facilitate the mechanical fibrillation of the fibers, e.g. swelling of thefibers etc. lt is preferred that the MFC produced from non-chemical modified Iignocellulosic material is MFC produced from mechanical pulp. Mechanicalpulp means pulp produced by subjecting wood fibers to mechanical energycausing the bonds between the fibers of the wood to break and fibers andfiber fragments to be released. ln the definition of mechanical pulp isgroundwood pulp, e.g. stone groundwood pulp (SGP) or pressuregroundwood (PGW) pulp, as well as thermomechanical pulp (TMP) orchemimechanical pulp (CTMP) included. The MFC from mechanical cellulosicpulp is referred to as mechanical MFC.
    With chemical modified Iignocellulosic material is meant Iignocellulosicmaterial that has been chemically modified with at least one chemical wheresaid chemical degrades the Iignocellulosic material. The chemical modifiedIignocellulosic material is preferably chemical pulp, i.e. the MFC fromchemical modified Iignocellulosic material is preferably MFC made fromchemical pulp, e.g. kraft pulp or sulfite pulp in any known way, e.g. byenzymatic, mechanical and/or chemical treatments, also referred to aschemical MFC. lt has surprisingly been found that microfibrillated cellulose producedfrom non-chemical modified Iignocellulosic material, preferably mechanicalpulp, has the ability to block UV radiation. Even more surprising is that smallamounts of microfibrillated cellulose produced from non-chemical modifiedIignocellulosic material are sufficient in order to achieve good UV properties ine.g. a film or a composition. The reason to why the MFC from non-chemicalmodified Iignocellulosic material has UV blocking properties is not fullyunderstood. One theory is that microfibrillated cellulose produced from non-chemical modified Iignocellulosic material comprises all elements of wood, i.e.no elements have been removed unlike chemical MFC, and one or more of these elements gives the mechanical MFC UV blocking properties. Also, allelements of wood, such as lignin, are bound in the microfibrils of themechanical MFC. ln this way the MFC from non-chemical modifiedlignocellulosic material, preferably mechanical MFC, is a much safercompound to use as UV blocker compared to if the elements giving the UVblocking properties were added separately to a composition or in a film.
    The MFC film according to the invention is transparent or semi-transparent making it suitable for many different end uses. For some paper orpaperboard products, e.g. products made from Solid Bleached Sulphate(SBS) pulp, it is necessary to improve the UV properties of the productpreventing either the paper or paperboard per se and/or the product packedin a package produced by the paper or paperboard from being affected by theUV radiation. Thus, it is both possible to add a composition comprising themechanical MFC to a paper or paperboard furnish, a coating color, sizingcomposition or to laminate or extrude a MFC film comprising the mechanicalMFC to the surface of the paper or paperboard and thus improving the UVblocking properties of the paper or paperboard product. Furthermore, theMFC film according to the invention will have good OTR values even at highmoisture contents which make it suitable for end uses in high moistureenvironments, e.g. for liquid packaging boards or for packages used in hotterclimates having high humidity.
    The film preferably has a transmittance of at least 70% for radiation withwavelengths above 400nm meaning that the film is translucent or transparentfor the human eye (in the visible light area). The film preferably has atransmittance below 70% for radiation with wavelengths below 400nmmeaning that the film blocks radiation within the UV area. By the presentinvention it is thus possible to produce a film that blocks UV radiation but stillis transparent in the visible light area. The transmittance could be measuredwith any suitable spectrometer, e.g. Cary 100 Conc spectrophotometer withDRA CA-301 Integrating Sphere, at room temperature and at a relativehumidity of 50%. lt has been found advantageous to use MFC produced from non-chemical modified fibers from coconut shell in the film since the coconut fibershad very good UV blocking properties at the same time as they are normallyFDA approved, i.e. approved for use in food packages.
    The MFC film having UV blocking properties is produced by providing afirst suspension comprising microfibri|ated cellulose produced frommechanica| pulp, conducting the first suspension to a wire and thereafterdewatering the first suspension to form a film. The dewatering may be doneon the wire or in subsequent conventional dewatering equipment. lt may bepreferred that the MFC film also comprises chemical MFC. Thus, the methodto produce the film may also comprise the steps of providing a secondsuspension comprising microfibri|ated cellulose produced from chemical pulp,mixing the first and second suspension whereby a mixture is obtained,conducting the mixture to a wire and thereafter dewater the mixture to formthe film. Thus, the first suspension comprising mechanica| MFC is conductedto a wire and dewatered together with the second suspension as a mixture.
    The first suspension or the mixture may be provided onto a porous wireof a paper making machine to form a web, i.e. any kind of paper makingmachine known to a person skilled in the art used for making paper,paperboard, tissue or any similar products. The formed web is thendewatered and may then subsequently be dried to form a film. Any conventional dewatering or drying equipment may be used.
    The film formed may be then be calendered. The final density, filmproperties and moisture content may thus be adjusted in the calender. Knowntechniques such as hard-nip, soft-nip, soft-hard nip, cylinder or belt, in variousforms and combinations can be used.
    The MFC film may also comprise other UV blocking additives, such asbenzotriazole based organic compounds, titanium dioxide, zinc oxide etc.
    Depending on the end use of the MFC film according to the invention it mightbe necessary to even further improve the UV blocking properties of the film byadding other commonly used UV blocking additives. However, the use ofmechanical MFC reduces the use/need of other additives which makes itpossible to use lower amounts of other UV blocking additives which bothmakes it more cost efficient as well as environmental friendly.
    The MFC film according to the invention may be used in free standingpouches, packages for dairy products or fatty food. lt may also be used as alayer on a paper or paperboard substrate to improve the UV blockingproperties of a paper or paperboard product. lt can also be used as a windowfilm to reduce the UV radiation through windows.
    The composition comprising microfibrillated cellulose produced frommechanical pulp may be a paint. With paint means a liquid that converts to asolid film after a thin layer of the paint has been applied to a substrate.Primers, lacquers or colored paints are including in the definition of paint. Thepresence of the mechanical MFC in the paint does not only give the paint UVresistance properties but it also has the advantage that it increases theviscosity of the paint. Normally additives for improving the viscosity are addedto paint compositions in order for the paint to get the necessary viscosity. Byusing mechanical MFC as an additive in the paint both improved UVresistance and viscosity are achieved.
    The composition may be sunscreen. Sunscreens are creams mostoften used on the skin in order to reduce the harmful effects of UV radiation.The use of mechanical MFC in sunscreens will make it possible to reduce oreven eliminate the other UV blockers normally used in sunscreens today, e.g.titanium dioxide or zinc oxide.
    The composition may be a coating color. Coating color comprisingpigments, fillers etc is used for improving the printing properties of e.g. apaper or paperboard product. By adding mechanical MFC to a coating color 11 the viscosity of the coating color will also improve. Thus, it is possible by thepresent invention to provide a coating color having both improved UVresistance and viscosity. The coating color comprising mechanical MFCaccording to the present invention may be added to a paper or paperboardproduct by any known conventional coating techniques.
    The composition may be a sizing composition. Sizing compositions isnormally used in paper or paperboard products to reduce the products abilityto absorb water. Sizing compositions may be used as internal sizing, i.e. thesizing composition may be added to a furnish during production of the paperor paperboard product or it can be used as surface sizing, i.e. the sizingcomposition is added to the surface of the paper or paperboard product. Thesizing composition may be added in by using any conventional sizingequipment.
    The composition may also be a wood impregnation solution. Woodimpregnation solutions are used to improve the characteristics of wood, e.g.to increase the strength, improve its' resistance to water, moisture orchemicals and/or to improve its' resistance against wood rot or otherbiological deteriorations. By adding mechanical MFC to a wood impregnationsolution the treated wood will then also have improved UV resistancepreventing the wood to be bleached or in any other way negatively affectedby UV radiation. The wood impregnation solution may be added by anyconventional method, e.g. by spraying the solution to the wood, dip the woodin the solution etc.
    The composition may be a yarn. lt is a big advantage in some fields tobe able to make yarns having good UV blocking properties.
    The composition may be a composite comprising a polymer, preferably athermoplastic polymer material selected from the group comprisingpolyethylene, polypropylene, polylactic acid, polystyrene, polycarbonate,polyvinyl chloride, acrylonitrile butadiene styrene, ethylene vinyl acetate 12 and/or derivates, and/or co-polymers, and/or mixtures thereof. The polymercontent of the composition is preferably from 10 to 80 weight-% of the dryweight of the suspension of said fibrous material and said polymer material. ltis of importance to provide composite materials used for example in screwcaps with UV blocking properties.
    Microfibrillated cellulose (MFC) shall in the context of the patentapplication mean a nano scale cellulose particle fiber or fibril with at least onedimension less than 100 nm. MFC comprises partly or totally fibrillatedcellulose or lignocellulose fibers. The liberated fibrils have a diameter lessthan 100 nm, whereas the actual fibril diameter or particle size distributionand/or aspect ratio (length/width) depends on the source and themanufacturing methods. The smallest fibril is called elementary fibril and hasa diameter of approximately 2-4 nm (see e.g. Chinga-Carrasco, G., Cellulosefibres, nanofibrils and microfibrils,: The morphological sequence of MFCcomponents from a plant physiology and fibre technology point of view,Nanoscale research letters 2011, 6:417), while it is common that theaggregated form of the elementary fibrils, also defined as microfibril (Fengel,D., Ultrastructural behavior of cell wall polysaccharides, Tappi J., March 1970,Vol 53, No. 3.), is the main product that is obtained when making MFC e.g. byusing an extended refining process or pressure-drop disintegrationprocess. Depending on the source and the manufacturing process, the lengthof the fibrils can vary from around 1 to more than 10 micrometers. A coarseMFC grade might contain a substantial fraction of fibrillated fibers, i.e.protruding fibrils from the tracheid (cellulose fiber), and with a certain amountof fibrils liberated from the tracheid (cellulose fiber).
    There are different acronyms for MFC such as cellulose microfibrils,fibrillated cellulose, nanofibrillated cellulose, fibril aggregates, nanoscalecellulose fibrils, cellulose nanofibers, cellulose nanofibrils, cellulosemicrofibers, cellulose fibrils, microfibrillar cellulose, microfibril aggregrates andcellulose microfibril aggregates. MFC can also be characterized by variousphysical or physical-chemical properties such as large surface area or itsability to form a gel-like material at low solids (1-5 wt%) when dispersed inwater. The cellulose fiber is preferably fibrillated to such an extent that thefinal specific surface area of the formed MFC is from about 1 to about 200 13 m2/g, or more preferably 50-200 m2/g when determined for a freeze-driedmaterial with the BET method.
    Various methods exist to make MFC, such as single or multiple passrefining, pre-hydrolysis followed by refining or high shear disintegration orliberation of fibrils. One or several pre-treatment step is usually required inorder to make MFC manufacturing both energy efficient and sustainable. Thecellulose fibers of the pulp to be supplied may thus be pre-treatedenzymatically or chemically, for example to reduce the quantity ofhemicellulose or lignin. The cellulose fibers may be chemically modifiedbefore fibrillation, wherein the cellulose molecules contain functional groupsother (or more) than found in the original cellulose. Such groups include,among others, carboxymethyl (CMC), aldehyde and/or carboxyl groups(cellulose obtained by N-oxyl mediated oxidation, for example "TEMPO"), orquaternary ammonium (cationic cellulose). After being modified or oxidized inone of the above-described methods, it is easier to disintegrate the fibers intoMFC or nanofibrillar size or NFC.
    The nanofibrillar cellulose may contain some hemicelluloses; theamount is dependent on the plant source. Mechanical disintegration of thepre-treated fibers, e.g. hydrolysed, pre-swelled, or oxidized cellulose rawmaterial is carried out with suitable equipment such as a refiner, grinder,homogenizer, colloider, friction grinder, ultrasound sonicator, fluidizer such asmicrofluidizer, macrofluidizer or fluidizer-type homogenizer. Depending on theMFC manufacturing method, the product might also contain fines, ornanocrystalline cellulose or e.g. other chemicals present in wood fibers or inpapermaking process. The product might also contain various amounts ofmicron size fiber particles that have not been efficiently fibrillated.
    MFC is produced from wood cellulose fibers, both from hardwood or softwoodfibers. lt can also be made from microbial sources, agricultural fibers such aswheat straw pulp, bamboo, bagasse, or other non-wood fiber sources. lt ispreferably made from pulp including pulp from virgin fiber, e.g. mechanical,chemical and/or thermomechanical pulps. lt can also be made from broke orrecycled paper.
    The above described definition of MFC includes, but is not limited to,the new proposed TAPPI standard W13021 on cellulose nanofibril (CMF) 14 defining a cellulose nanofiber material containing multiple elementary fibrilswith both crystalline and amorphous regions, having a high aspect ratio withwidth of 5-30nm and aspect ratio usually greater than 50.
    According to one embodiment the MFC may have a Schopper Rieglervalue (SR°) of more than 87. The Schopper-Riegler value can be obtainedthrough the standard method defined in EN ISO 5267-1. This high SR valueis determined for a repulped wet web, with or without additional chemicals,thus the fibers have not consolidated into a film or started e.g. hornification.
    The dry solid content of this kind of web, before disintegrated andmeasuring SR, is less than 50 % (w/w). To determine the Schopper Rieglervalue it is preferable to take a sample just after the wire section where the wetweb consistency is relatively low.
    The skilled person understands that paper making chemicals, such asretention agents or dewatering agents, have an impact on the SR value.
    The SR value specified herein, is to be understood as an indication butnot a limitation, to reflect the characteristics of the MFC material itself.However, the sampling point of MFC might also influence the measured SRvalue. For example, the furnish could be either a fractionated orunfractionated suspension and these might have different SR values.Therefore, the specified SR values given herein, are thus either a mixture ofcoarse and fine fractions, or a single fraction comprising an MFC gradeproviding the desired SR value.
    ExampleChemimechanical softwood pulp was fluidized 10 times in a fluidizer toproduce mechanical MFC.
    MFC films comprising different amounts of mechanical MFC wasproduced. The mechanical MFC was mixed with chemical MFC to form filmscomprising less than 100% of mechanical MFC. The chemical MFC wasproduced by enzymatically treating kraft pulp with an endoglucanase enzymeat 50°C for 3 hours followed by increasing the temperature to 90°C todeactivate the added enzymes. The enzymatic treated pulp was thereafter fibrillated using a fluidizer at a consistency of 3% in order to produce chemicalMFC.
    The mechanical MFC and chemical MFC was mixed and formed to aMFC film. The transmittance of the films was measured using a Cary 100Conc spectrophotometer with DRA CA-301 Integrating Sphere at roomtemerature and at a relative humidity (RH) of 50%.
    The results from the tests can be seen in Figure 1. Figure 1 shows thatthe transmittance for the films comprising low amounts of mechanical MFChas low transmittance within the UV area and a high transmittance outsidethe UV area, e.g. in the visible light area. lt is ideal to have low transmittancewithin the UV area and high transmittance in the visible light area. Thus, bythe present invention it is possible to produce a transparent or at least semi-transparent film having good UV blocking properties, even at low addition ofmechanical MFC. ln view of the above detailed description of the present invention, othermodifications and variations will become apparent to those skilled in the art.However, it should be apparent that such other modifications and variationsmay be effected without departing from the spirit and scope of the invention.
    权利要求:
    Claims (1)
    [1] 1. An UV blocking film comprising microfibrillated cellulose wherein at leastpart of the microfibrillated cellulose is microfibrillated cellulose producedfrom non-chemical modified lignocellulosic material. The film according to claim 1 wherein the non-chemical modifiedlignocellulosic material is mechanical pulp. The film according to claim 2 wherein the mechanical pulp ischemithermomechanical pulp (CTMP), thermomechanical pulp (TMP),pressure groundwood (PGW) pulp and/or stone groundwood pulp(SGP). The film according to claim 1 wherein the lignocellulosic material is fiberfrom coconut shell. The film according to any of the preceding claims wherein the filmcomprises 2.5-50% by weight of fiber based material of microfibrillatedcellulose produced from non-chemical modified lignocellulosic material,preferably between 5-40% by weight. The film according to any of the preceding claims wherein the film alsocomprises microfibrillated cellulose produced from chemical modifiedlignocellulosic material, preferably from chemical pulp. The film according to claim 6 wherein the film comprises 50-97.5% byweight of fiber based material of microfibrillated cellulose produced fromchemical modified lignocellulosic material, preferably between 60-95%by weight. The film according to any of the preceding claims wherein the film alsocomprises nano-fillers, preferably nano-precipitated calcium carbonate(PCC), nano-fillers from bentonite, nano-fillers from titanium dioxide, 10. 11. 12. 13. 14. 17 nano-fillers from zinc oxide, nano talc, nano clays and/or other nanosized fillers. The film according to any of the preceding claims, wherein the film has abasis weight of less than 50 g/m2, or less than 35 g/m2, or less than 25g/m2.The film according to any of the preceding claims wherein the film has atransmittance of at least 70% for radiation with wavelengths above400nm. The film according to any of the preceding claims wherein the film has atransmittance below 70% for radiation with wavelengths below 400nm. A method for manufacturing a film having UV blocking propertieswherein the method comprises the steps of:- providing a first suspension comprising microfibrillated celluloseproduced from non-chemical modified lignocellulosic material,- conducting the first suspension to a wire and- dewatering the first suspension to form a film. The method as claimed in claim 12, wherein said method furthercomprises the steps of:- providing a second suspension comprising microfibrillated celluloseproduced from chemical modified lignocellulosic material and- mixing the first and second suspension whereby a mixture isobtained,- conducting the mixture to a wire and thereafter - dewatering the mixture to form the film The method as claimed in any of the claims 12-13, wherein themicrofibrillated cellulose has a Schopper Riegler value (SR°) of morethan 87 SR °. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 18 The method according to any of the c|aims 12-14 wherein the mixturecomprises the first suspension in an amount of 2.5-50% by weight of thefiber based material and the second suspension in an amount of 50-97,5% by weight of the fiber based material. The method according to any of the c|aims 12-15 wherein nano-filler, preferably nano-precipitated calcium carbonate (PCC), nano-fillers frombentonite, nano-fillers from titanium dioxide, nano-fillers from zinc oxide,nano talc, nano clays and/or other nano sized fi|ers is added to the first suspension and/or second suspension. A composition having UV blocking properties wherein said compositioncomprises microfibri|ated cellulose produced from non-chemicalmodified lignocellulosic material. The composition according to claim 17 wherein the compositioncomprises 2.5-50% by weight of fiber based material of microfibri|atedcellulose produced from non-chemical modified |ignoce|u|osic material. The composition according to any of the c|aims 17-18 wherein thecomposition is a paint. The composition according to any of the c|aims 17-18 wherein thecomposition is a sunscreen. The composition according to any of the c|aims 17-18 wherein thecomposition is a coating color. The composition according to any of the c|aims 17-18 wherein thecomposition is a sizing composition. The composition according to any of the c|aims 17-18 wherein the composition is a wood impregnation solution. The composition according to any of the c|aims 17-18 wherein thecomposition is a composite comprising a polymer. 19 25. Use of the composition according to claim 24 for making a screw cap. 26. Use of the film according to any of the claims 1-11 as a window film oron the surface of a paper or paperboard product.
    类似技术:
    公开号 | 公开日 | 专利标题
    US10752741B2|2020-08-25|UV blocking film and composition comprising microfibrillated cellulose, a method for producing said film and use of the composition
    EP3350371B1|2020-02-19|Surface sizing of dense films
    EP3475485B1|2021-04-21|Microfibrillated film
    FI123289B|2013-01-31|Process for the preparation of nanofibrillated cellulosic pulp and its use in papermaking or nanofibrillated cellulose composites
    EP3350369B1|2019-07-24|A method to produce a film comprising microfibrillated cellulose and an amphoteric polymer
    CA2995478A1|2017-03-23|A method for producing a film having good barrier properties
    US20190276619A1|2019-09-12|Method for forming a film comprising nanocellulose
    CA3079132A1|2019-04-25|A method for producing a film having good barrier properties and a film having good barrier properties
    US11161948B2|2021-11-02|Film comprising microfibrillated cellulose and products made therefrom
    WO2019171279A1|2019-09-12|A method for producing a film having good barrier properties and improved strain at break
    BR112020015781A2|2020-12-15|PROCESS FOR PRODUCTION OF A FILM | UNDERSTANDING MICROFIBRILLATED CELLULOSE
    WO2018185611A1|2018-10-11|Heat sealable packaging material comprising microfibrillated cellulose and products made therefrom
    CA3138725A1|2020-11-05|Novel laminated veneer lumber product and method for manufacturing thereof
    BR112020017828A2|2020-12-29|METHOD FOR MANUFACTURING A COMPOSITION UNDERSTANDING MICROFIBRILLATED CELLULOSIS
    同族专利:
    公开号 | 公开日
    EP3458506A4|2019-11-06|
    JP2019526000A|2019-09-12|
    BR112018073560A2|2019-03-19|
    CN109153798B|2022-01-11|
    US10752741B2|2020-08-25|
    JP6963564B2|2021-11-10|
    US20190292337A1|2019-09-26|
    CN109153798A|2019-01-04|
    CA3022522A1|2017-11-23|
    WO2017199157A1|2017-11-23|
    EP3458506A1|2019-03-27|
    SE539950C2|2018-02-06|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US6183596B1|1995-04-07|2001-02-06|Tokushu Paper Mfg. Co., Ltd.|Super microfibrillated cellulose, process for producing the same, and coated paper and tinted paper using the same|
    US6432517B1|1998-11-21|2002-08-13|Asahi Glass Company Ltd.|Recording sheet and process for producing it|
    ES2394934T3|2007-05-09|2013-02-06|Institute Of Natural Fibres And Medicinal Plants|Textile materials of cellulose fibers containing nanolignins, method of application of nanolignins on textile materials and use of nanolignins in the production of textile materials|
    PT3095912T|2008-04-03|2019-05-28|Innventia Ab|Composition for coating of printing paper|
    GB0908401D0|2009-05-15|2009-06-24|Imerys Minerals Ltd|Paper filler composition|
    SE533510C2|2009-07-07|2010-10-12|Stora Enso Oyj|Method for producing microfibrillar cellulose|
    RU2567855C2|2009-11-16|2015-11-10|Тетра Лаваль Холдингз Энд Файнэнс С.А.|Strong paper|
    FI123289B|2009-11-24|2013-01-31|Upm Kymmene Corp|Process for the preparation of nanofibrillated cellulosic pulp and its use in papermaking or nanofibrillated cellulose composites|
    FI20105272A|2010-03-18|2011-09-19|Univ Helsinki|Method for fibrillation of lignocellulosic material, fibers and their use|
    WO2011125801A1|2010-04-01|2011-10-13|三菱化学株式会社|Process for production of fine cellulose fiber dispersion|
    US9856607B2|2010-05-11|2018-01-02|Fpinnovations|Cellulose nanofilaments and method to produce same|
    SE536744C2|2010-05-12|2014-07-08|Stora Enso Oyj|A process for manufacturing a composition containing fibrillated cellulose and a composition|
    SE536746C2|2010-05-12|2014-07-08|Stora Enso Oyj|A composition containing microfibrillated cellulose and a process for making a composition|
    US8771463B2|2010-11-16|2014-07-08|Oji Holdings Corporation|Cellulose fiber assembly and method for preparing the same, fibrillated cellulose fibers and method for preparing the same, and cellulose fiber composite|
    AU2012208922B2|2011-01-21|2016-10-13|Fpinnovations|High aspect ratio cellulose nanofilaments and method for their production|
    PL2707540T3|2011-05-13|2016-12-30|Process for treating microfibrillated cellulose and microfibrillated cellulose treated according to the process|
    US8835141B2|2011-06-09|2014-09-16|The United States Of America As Represented By The Secretary Of Agriculture|Methods for integrated conversion of lignocellulosic material to sugars or biofuels and nano-cellulose|
    SE536780C2|2011-10-26|2014-08-05|Stora Enso Oyj|Process for preparing a dispersion comprising nanoparticles and a dispersion prepared according to the process|
    FI124748B|2011-11-15|2015-01-15|Upm Kymmene Corp|Paper product and method and system for preparing the mixture ratio|
    US20150017432A1|2012-03-06|2015-01-15|Yissum Research Development Company of the Herbrew University of Jerasalem Ltd.|Coating layers of a nanocomposite comprising a nano-cellulose material and nanoparticles|
    JP2013194192A|2012-03-22|2013-09-30|Asahi Kasei Chemicals Corp|Ultraviolet light-cutting film|
    EP2653508A1|2012-04-19|2013-10-23|Imerys S.A.|Compositions for paint|
    FI124235B|2012-04-26|2014-05-15|Stora Enso Oyj|Fiber-based paper or paperboard web and a process for its manufacture|
    FI127111B|2012-08-20|2017-11-15|Stora Enso Oyj|Process and intermediate for producing highly processed or microfibrillated cellulose|
    US8906198B2|2012-11-02|2014-12-09|Andritz Inc.|Method for production of micro fibrillated cellulose|
    CN104812263B|2012-11-05|2017-11-10|地方独立行政法人京都市产业技术研究所|The manufacture method of secure component and secure component|
    SE537517C2|2012-12-14|2015-05-26|Stora Enso Oyj|Wet-laid sheet material comprising microfibrillated cellulosic process for making them|
    FI127682B|2013-01-04|2018-12-14|Stora Enso Oyj|A method of producing microfibrillated cellulose|
    ES2688579T3|2013-06-20|2018-11-05|Basf Se|Production procedure of a microfibrillated cellulose composition|
    WO2015052625A1|2013-10-07|2015-04-16|Basf Se|Manufacture of paper and paperboard containing wood free pulp|
    JP6243819B2|2014-09-05|2017-12-06|大王製紙株式会社|Cellulose nanofiber, structure, laminate and method for producing cellulose nanofiber|
    AU2015338731A1|2014-10-28|2017-05-18|Stora Enso Oyj|A method for manufacturing microfibrillated polysaccharide|
    JP6091589B2|2015-03-19|2017-03-08|国立大学法人京都大学|Fiber reinforced resin composition containing chemically modified cellulose nanofiber and thermoplastic resin|
    JP6575128B2|2015-05-12|2019-09-18|凸版印刷株式会社|Method for producing cellulose nanofiber sheet|
    CN108474182B|2016-01-05|2021-09-28|斯道拉恩索公司|Method of forming a complex comprising MFC and complexes produced by said method|
    SE539833C2|2016-04-01|2017-12-12|Stora Enso Oyj|Process for production of film comprising microfibrillated cellulose|
    SE1650900A1|2016-06-22|2017-11-28|Stora Enso Oyj|Microfibrillated cellulose film|
    SE540511C2|2016-11-18|2018-09-25|Stora Enso Oyj|Method for making a film comprising mfc|SE538770C2|2014-05-08|2016-11-15|Stora Enso Oyj|Process for making a thermoplastic fiber composite material and a fabric|
    SE1650900A1|2016-06-22|2017-11-28|Stora Enso Oyj|Microfibrillated cellulose film|
    SE540365C2|2016-09-28|2018-08-14|Stora Enso Oyj|A method for the production of a film comprising microfibrillated cellulose, a film and a paper or paperboard product|
    CA3068732A1|2017-06-30|2019-01-03|Harshad PANDE|Light-selective mulch|
    EP3741354A1|2019-05-23|2020-11-25|Nature Costech Co., Ltd.|Sunscreen agent comprising cellulose nanofibers|
    SE1950802A1|2019-06-27|2020-12-28|Stora Enso Oyj|Gas barrier film for packaging material|
    WO2022011316A1|2020-07-10|2022-01-13|University Of Maryland, College Park|Modified wood and transparent wood composites, and systems and methods for forming and use thereof|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    SE1650690A|SE539950C2|2016-05-20|2016-05-20|An uv blocking film comprising microfibrillated cellulose, amethod for producing said film and use of a composition hav ing uv blocking properties|SE1650690A| SE539950C2|2016-05-20|2016-05-20|An uv blocking film comprising microfibrillated cellulose, amethod for producing said film and use of a composition hav ing uv blocking properties|
    JP2018557309A| JP6963564B2|2016-05-20|2017-05-15|UV shielding films and compositions containing microfibrillated cellulose, methods of producing the films, and use of the compositions.|
    BR112018073560-4A| BR112018073560A2|2016-05-20|2017-05-15|ultraviolet blocking film and composition comprising microfibrillated cellulose, method for producing said film and use of said composition|
    PCT/IB2017/052856| WO2017199157A1|2016-05-20|2017-05-15|A uv blocking film and composition comprising microfibrillated cellulose, a method for producing said film and use of the composition|
    US16/302,813| US10752741B2|2016-05-20|2017-05-15|UV blocking film and composition comprising microfibrillated cellulose, a method for producing said film and use of the composition|
    EP17798849.0A| EP3458506A4|2016-05-20|2017-05-15|A uv blocking film and composition comprising microfibrillated cellulose, a method for producing said film and use of the composition|
    CN201780030829.8A| CN109153798B|2016-05-20|2017-05-15|UV-blocking film and composition comprising microfibrillated cellulose, method for producing said film and use of said composition|
    CA3022522A| CA3022522A1|2016-05-20|2017-05-15|A uv blocking film and composition comprising microfibrillated cellulose, a method for producing said film and use of the composition|
    [返回顶部]